Low - energy electron collisions with tetrafluoroethene , C 2 F 4

Articles you may be interested in Elastic and inelastic cross sections for low-energy electron collisions with pyrimidine Interaction of low-energy electrons with linear diphenylethynyl derivatives in the gas phase We report calculated cross sections for elastic and inelastic collisions of low-energy electrons with tetrafluoroethene, C 2 F 4. The elastic cross section shows a number of resonance features, which we classify according to symmetry and analyze in relation to available experimental data. Electron-impact excitation cross sections are obtained for the 1 3 B 1u (T) and 1 1 B 1u (V) states arising from the ␲→␲* transition, as well as for eight other low-lying excited states arising from excitations out of the highest occupied molecular orbital. As expected, the T and V states make the largest individual contributions to electron-impact excitation at low energies; however, the other states are shown to contribute significantly to the total excitation cross section at impact energies from 10 to 25 eV.